Ivo Graham takes on Fern Brady, whilst Tom Rosenthal battles Chris Ramsey.
Former couple Alfie Brown and Jessie Cave roast each other, and Daniel Sloss takes on Phil Wang.
Real-life couple Catherine Bohart and Sarah Keyworth battle it out, as do Mark Watson and Andrew Maxwell.
Stephen Bailey takes on Darren Harriott, and Angela Barnes takes on Matt Richardson.
Edinburgh Comedy Award winner Rose Matafeo battles Naz Osmanoglu, whilst disabled comics Alex Brooker and Rosie Jones also compete.